Some educational mathematics sites:
   Centre for Innovation in Maths Teaching
Various resources from Exeter University
   CUP/Univ of Cambridge Local Exam Board
Various resources for teachers and students
   GCSE Answers site
GCSE papers and model answers, plus tutorials on various topics
   Math.com
An American site with lots of resources for teachers
   Birmingham Council
Some useful resources: lesson starters and investigations
Some useful Maths Links pages:
...and, of course, there's Yahoo! or Google.